DP 5505

Name: DP 5505
Brand: Interflux Electronics
SKU: DP-5505

high stability solder paste

Reflow soldering is the most used soldering process in electronics assembly. Mainly SMD (Surface Mount Device) components but also some through hole components are soldered in a reflow oven to a PCB (Printed Circuit Board) by means of a solder paste. The reflow oven is usually a forced convection oven but also vapor phase and IR ovens are possible. The first step of the process is to apply solder paste to the pads of the PCB or in case of through hole components in the through hole. This latter is called Pin in Paste (PiP) or intrusive reflow technology. The main application method is stencil printing but also dispensing and solder paste jetting are possible. Depending on the application method the solder paste will have a different consistency and comes in a different packaging. Solder paste is a mixture of a solder powder and a gel flux. The type of gel flux and the type of powder and in what ratios they are mixed, will determine the consistency of the paste. The solder powder is made of a certain soldering alloy and has a certain grain size (distribution). Finer grains size are used for smaller pitch components and smaller stencil apertures. Dispensing and even more jetting also require finer grain sizes. The gel flux contains substances to deoxydize the surfaces to be soldered. It also contains substances that will determine the consistency and the behavior of the solder paste in the process to a great extent. When stencil printing solder paste, an important parameter is that the solder paste keeps its printing properties during the time it will be on the stencil. This is often referred to as the stability of the solder paste. Solder paste stability is hard to quantify but can be estimated from the stencil life indication in the technical datasheet. After solder paste application SMD components are placed on the solder paste with their solderable connections. In most cases, this is done with a Pick and Place machine. The solder paste needs to have enough adhesion force to keep the components in their place until soldering. A conveyor will transport the PCB through a reflow oven where the PCB board is submitted to a reflow soldering profile. This profile is created by the temperature settings of the different convection zones. They are usually situated as well from the top as from the bottom side. Beside the temperature settings, in some cases also the convection rate of the zones can be programmed to get better or lower heat transfer, or when some high components experience too much force from the convection. It is the goal to get all components to soldering temperatures, which is determined by the used soldering alloy, without damaging or overheating temperature sensitive components. This can be a challenge for units with a large diversity of big and small components or an uneven Cu-distribution in the PCB board. In that perspective a low melting point soldering alloy substantially limits the risk of damaging or predamaging components and PCB boards. The speed of the conveyor will determine the time of the profile and the throughput of the oven. In most cases however the Pick and Place process is limiting the throughput. Not all electronic components are suitable for reflow soldering. Some because of their thermal mass like e.g. big transfos or others because of their thermal sensitivity like e.g. some displays, connectors, relays, fuses,... These components are usually available as a through hole components and soldered in other processes like selective soldering, wave soldering, hand soldering, robot soldering, laser soldering,...
Stencil printing is the most used method to apply solder paste on the pads of a PCB (Printed Circuit Board) in the SMT (Surface Mount Technology) assembly line in electronics manufacturing. After stencil printing, SMD (Surface Mount Device) components are placed with their solderable contacts on the solder paste and the PCB is transported through a reflow oven where the components are soldered to the PCB board. Stencil printing can also be used to apply solder paste in trough holes for the Pin in Paste (PiP, intrusive reflow) technology that is meant to solder through hole components in the reflow soldering process . Stencil printing can also be used to apply SMT adhesive (glue) to the PCB board. SMD components are placed with their body on the glue that will be cured in a reflow oven. After that, the SMD components that are glued to the PCB board will be soldered in a wave soldering process. The PCB board is pressed onto a stencil that has apertures where the solder paste needs to be deposited. A volume of solder paste is present on the stencil. A squeegee is lowered onto the stencil with a certain pressure. The squeegee moves over the stencil with a certain printing speed. This will make the solder paste roll into the apertures. The printing speed can be determined by the desired throughput, typical for high volume productions but can be limited by the used solder paste. This speed can vary from 20-150 mm/s. Once the desired speed has been established, a printing pressure will have to be determined for that printing speed. Higher speeds require higher pressures. The correct printing pressure is the minimum pressure needed to get a clean stencil after printing, meaning all excessive solder paste has been removed by the squeegee. The board is moved away vertically from the stencil, the solder paste releases from the stencil and pads of the PCB have solder paste deposits. The goal is to have a well defined printing result where all solder paste has realeased from the stencil and no solderpaste has been pressed between the stencil and the PCB board. The release of the solder paste obviously is more difficult for smaller apertures and thicker stencils. Some design rules say that the ratio of the surface of the aperture to the surface of the sides ('walls') of the aperture is preferrably not smaller than 0,6. The quality of the stencil is a major parameter in good paste release. Rough sides are more likely to adhere solder paste. Different types of stencils exist. The most popular is the stainless steel stencil with laser cut apertures that are smoothened afterwards by a chemical process. Sometimes they are treated with a coating for better paste release. The main reasons for solder paste being pressed in between the stencil and the PCB board is bad sealing between board and stencil or too high printing pressure for the used printing speed. This can lead to solder balling or bridging after reflow. Some printing machines have an automated under stencil cleaning unit that can be programmed to clean the stencil after so many prints. This will facilitate a stable printing result. It is advisable not to use IPA based or water based cleaning liquids in these units as they may affect the solder paste stability. The use of products that have been specifically designed for that purpose is advisable. The stability of the solder paste on the stencil, meaning how well that the solder paste keeps its printing properties over time, is also a parameter for a stable printing process. Some printing machine have integrated AOI (Automated Optical Inspection) that will check the printing result and give an alarm if it deviates from the programmed desired values. This will help to avoid electronic units being produced with solder joints that are not according good standard.
Dispensing is a technology used in electronics manufacturing to apply solder paste (or an adhesive) from a syringe to a PCB (Printed Circuit Board). Dispensing is a more flexible way to apply solder paste than standard stencil printing because it allows to selectively apply solder paste with the presence of pre-assembled components on the surface. However dispensing is a much slower process than stencil printing and not suitable for high volume productions. That's why it is mostly used to add extra solder paste in an SMT (Surface Mount Technology) assembly line but also for rework and repair and in prototyping. Dispensing can be done manually or automatically. In rework and repair this is usually done manually with a system that applies pressurised air to the plunger of the syringe and the solder paste is pushed out through a needle. But it can also be done by hand with a manual plunger. In automated processes like in a stand alone dispenser in a SMT assembly line or a in a dispenser built in a stencil printer there are two main systems to push the solder paste out of the syringe: Air pressure and the Archimes screw. Air pressure systems are usually cheaper but the volumetric stability of the solder paste deposits is a bit more difficult to control, especially when the syringe is almost empty and there is a bigger volume of compressed air in combination of less material in the syringe that needs to be moved by this air pressure. Systems with the Archimedes screw are usually more stable and faster. However depending on the solder paste quality, they can be sensitive to some very fine particles of the solder paste that are squashed between the Archimedes screw and the side walls which can block the needle where the solder paste comes out. The smaller and longer the needle, the higher the risk on needle blocking. The needle size is chosen according to the size of the desired solder deposit. The grain size of the solder paste is chosen according to this needle size. In general a type 3 solder paste can be used for needles with an inner diameter bigger than 0,5mm, a type 4 for needles with an inner diameter down to 0,25mm, a type5 for needles with an inner diameter down to 0,15mm. The dispensing performance of a solder paste can vary from one type to another in terms of volumetric stability and sensitivity to needle blocking. If a syringe of solder paste has been stored too long, too warm or too cold, this can also affect the dispensing performance. How much time and temperature will affect the dispensing performance may also vary from one solder paste to another. Solder paste for dispensing can be available in different types of syringes required by the machine where its intended use is for. They can also be available with different types of plungers required by the viscosity of the solder paste to be dispensed. Standard sizes for syringes are 5CC, 10CC and 30CC.
Lead-free soldering
Lead-based soldering

Key advantages

Long stencil life, high stability
High printing speeds
Voids are air pockets in solder joints. The gasses produced during soldering do not find their way out of the liquid soldering alloy and are trapped upon solidification. They are typically found on components where the solder joint, or a big part of it, is covered by the body of the component like BGAs, LGAs, QFNs, LED's,... Voids are typically being detected using Xray machines. Voiding is more significantly present with Sn(Ag)Cu lead-free soldering alloys where void levels are typically between 20-30% but can go up to 50%. This can cause inferior electrical and thermal conductivity which can, depending on the application lead to failures. Also the mechanical strength of the solder joint can be affected by these voids. This can be problemeatic for applications that are submitted to (thermo)mechanical forces in the field like vibration, mechanical shock, thermal cycling, thermal shock,...Void levels can also vary depending on the type of solder paste used and the soldering profile. Low melting point soldering alloys like LMPA-Q typically have void levels below 10%. In the field void levels can for example be reduced by using a reflow soldering machine with a vacuum chamber, by adapting the soldering profile (a soak profile is often preferred to a ramp profile), by chosing the correct solder paste, by adapting the stencil design for solder paste printing or by changing the PCB finishing.
Reduced head-in-pillow defect
Absolutely halogen free soldering chemistry contains no intentionally added halogens nor halides. The IPC classification allows up to 500ppm of halogens for the lowest 'L0' classification. Soldering fluxes, solder pastes and solder wires from this class are often referred to as 'halogen free'. Absolutely halogen free soldering chemistry goes one step further and does not contain this 'allowed' level of halogens. Specifically in combination with lead-free soldering alloys and on sensitive electronic applications, these low levels of halogens have been reported to cause reliability problems like e.g. too high leakage currents. Halogens are elements from the periodic table like Cl, Br, F and I. They have the physical property that they like to react. This is very interesting from the point of view of soldering chemistry because it is intended to clean off oxides from the surfaces to be soldered. And indeed halogens perform that job very well, even hard to clean surfaces like brass, Zn, Ni,...or heavily oxidized surfaces or degraded I-Sn and OSP (Organic Surface Protection) can be soldered with the aid of halogenated fluxes. Halogens provide a great process window in solderability. The problem however is that the residues and reaction products of halogenated fluxes can be problematic for electronic circuits. They usually have high hygroscopicity and high water solubility and give an increased risk on electro migration and high leakage currents. This means a high risk on malfunctioning of the electronic circuit. Specifically with lead-free soldering alloys there are more reports that even the smallest levels of halogens can be problematic for sensitive electronic applications. Sensitive electronic applications are typically high resistance circuits, measuring circuits, high frequency circuits, sensors,...That's why the tendency is to move away from halogens in soldering chemistry in electronics manufacturing. In general when the solderability of the surfaces to be soldered from component and PCB (Printed Circuit Board) are normal, there is no need for these halogens. Smartly designed absolutely halogen free soldering products will provide a large enough process window to clean the surfaces and get a good soldering result and this in combination with high reliability residues.
Rosin also known as colophony is a natural product coming from trees. There are many kinds of rosins with very different properties but some general properties apply. As a part of soldering chemistry, like soldering fluxes, solder pastes and solder wires, in general, rosin provides a large process window in the soldering process. This means that in general it is able to withstand longer times and higher temperatures than e.g. a resin. An advantage of the rosin in a liquid flux is that in general it tends to leave less solder balls on the solder mask after wave or selective soldering. Furthermore the rosin residue will give a certain protection against atmospheric moisture. This can provide an extra chance to pass climatic reliability tests. This protection capacity however degrades in time. On the other hand, rosin contained in a liquid soldering flux can also have some disadvantages. It increases the risk on blocking the spray nozzle or jet nozzle of wave and selective soldering machines. The residues left in the machine and on carriers are quite hard to clean off. Residues left on the PCB board can interfere with electrical pin testing (ICT, In Circuit Testing) and create a contactproblem causing a false reading/false error. In some cases this can lead to obstruction of the production flow. When some of the rosin containing flux spray accidentally ends up on contacts of e.g. a connector, a switch/relay/contactor with a partial open housing or on carbon contacts or on contact pattern on the PCB, this can also lead to contact problems. Rosin residues in general have poor compatibility with conformal coatings. After thermal cycling the conformal coating can start showing cracks where atmospheric moisture can penetrate and condensate. Considering all the above, weighing the advantages of rosin in liquid soldering fluxes against the disadvantages, there is an ongoing tendency to chose for liquid fluxes without rosin. 'OR' classified fluxes do not contain rosin. Rosin is very often used in solder wire because of its wide process window in time and temperature. The disadvantage is that rosin tends to discolor with temperature and leave visually heavy residues. When the solder wire is used for reworking electronic PCB boards, this residue is for some electronic manufacturers non desirable, as they do not like their customers to see that rework has been done on a PCB. Cleaning of these rosin residues requires special cleaning agents and is a time consuming process. In this case manufacturers can chose for an RE classified solder wire like IF 14. The residues are minimal and can be brushed away with a dry brush. Rosin is also used in solder pastes. Beside giving a good process window in time and temperature, it also provides a good stability of the solder paste on the stencil. This will facilitate a stable printing process and hence stable soldering results and defect rates. The discoloration of the rosin in reflow soldering is not so prominent as it is with a solder wire because the temperatures in reflow soldering are lower than in hand soldering. Still the rosin residue has poor compatibility with conformal coating and in time after thermal cycles it might show cracks or detatching of the conformal coating. Although most manufacturers will apply the conformal coating over the solder paste residues, for optimal results it is advisable to clean off the solder paste residues. Giving the benefits of colophony described above, most solder pastes contain colophony.
When a soldering product is labelled No-clean, this means that soldering product has passed reliability testing like a Surface Insulation Resistance(SIR) test or an electro(chemical) migration test. These tests are designed to test the hygroscopic properties of the residues of the soldering product under elevated temperature and high relative moisture conditions. No-clean is an indication that the residues can remain on the electronic unit after the soldering process without being cleaned. This will apply for by far most of the electronic applications. For very sensitive electronic applications, which are typically high resistance electronic circuits, high frequency electronic circuits, etc... it is possible that cleaning of the electronic unit is necessary. It is always the responsibility of the electronic manufacturer to judge wether cleaning is necessary or not.
Lead-free alloys are soldering alloys without Pb used to connect electronic components to PCB (Printed Circuit Board) boards in electronics manufacturing. In 2006 legislation restricted the use of lead (Pb) because of the risk that end-of-life electronics in land fills would pollute ground water and Pb would be introduced in the eco-system. When Pb is taken in by the human body, it is very hard to be removed and it is known to cause all kinds of (long term) health issues. In 2006 the use of lead (Pb) was restricted by legislation. For that reason, the industry was forced to look into alternatives without Pb. In the end, the industry standardised on Sn(Ag)Cu based soldering alloys. These alloys provided acceptable useability in the existing soldering processes in combination with sufficient mechanical reliabilty of the solder joints and good thermal and electrical properties. The main disadvantage of Sn(Ag)Cu alloys is their quite high melting points (or melting ranges) that result in quite high operating temperatures. This induces thermo-mechanical stress on the electronic unit in the soldering processes that can result in damage or predamage of some temperature sensitive PCB materials and components. Typical soldering temperatures in wave soldering are 250-280°C, in selective soldering 260-330°C and measured peakT° in reflow 235-250°C. The most popular alloy is the Sn96,5Ag3Cu0,5 alloy with melting temperature around 217°C, often referred to as SAC305. Other versions are SnAg4Cu0,5, SnAg3,8Cu0,7, SnAg3,9Cu0,6,...The differences in melting point between these alloys and the differences in terms of mechanical, electrical and thermal properties are for most electronic applications and soldering processes non significant. Because of cost reasons, the one with lowest Ag-content has the preference and that is the SAC 305. Also because of cost reasons, there is a trend towards low Ag SnAgCu alloys like e.g. Sn99Ag0,3Cu0,7, Sn98,5Ag0,8Cu0,7,... often referred to as low SAC alloys. These alloys have a melting range in between 217°-227°C. This in most cases will require higher working temperatures in the soldering processes up to 10°C, which for some temperature sensitive components can be significant. The mechanical, electrical and thermal properties of the low SAC alloys differ a bit more from the standard SAC alloys. In general they have a lower thermal cycling (fatigue) resistance but for most electronics applications this is not significant. The required 10°C higher working temperature however is often a problem in reflow soldering because most electronic units will have one or more temperature sensitive components. Furthermore, in general SMD (Surface Mount Device) solder joints are weaker than through hole soldered solder joints and SAC alloys in general have rather poor thermal cycling resistance, specifically on thin solder joints. Considering all these paremeters, in most cases the choice will be made for the standard SAC alloys and not the low SAC alloys for reflow soldering. For wave soldering the story is a bit different. The wave solder bath with a lead-free soldering alloy generates quite a lot of oxides becuase of its high working temperature. This is why a lot of manufacturers chose for closed nitrogen machines. This however requires investment in infrastructure which not every manufacturer is willing or able to do. The oxides generated, in genral are being sold back to the manufacturer of the soldering alloy where they are being recycled. The total cost for the electronics manufacturer in this matter is quite high, cetainly with the high Ag soldering alloys like SAC305. That's why there is a tendency towards the use of low SAC and even SnCu alloys (without Ag). Also here the higher melting point will require an increase in operating temperature to get acceptable through hole filling. As in most cases the heat is applied from the bottom side and to the leads of the components, the temperature sensitive components on top of the board in general do not suffer too much from this. In terms of mechanical reliability of the low SAC and SnCu alloy, this is less an issue because through hole soldered solder joints in general are much stronger than SMD joints. When (glued) SMD components are wave soldered on the bottom side of the PCB this can be different. Also when thermally heavy applications need to be soldered, the higher melting points can give a problem with good through hole fill and cases are known where the working temperature had to be raised so much that PCB material and some components from the top side were damaged. In those cases a low melting point soldering alloy is a good solution. Low melting point alloys that are SnBi based were never considered a viable alternative in the changeover from Pb containing to Pb free alloys because of there incompatibility with Pb and in the transition phase where still a lot of components and PCB materials contained Pb, it was impossible to use them. However since a couple of years the industry is starting reconsider the low melting point alloys because they have a lot of advantages and the risk on Pb contaminationhas become extremely low. A low melting point soldering alloy like e.g. LMPA-Q requires much lower operating temperatures than the standard lead-free soldering alloys. In reflow soldering it requires a peak T° of 190°C-210°C, in wave soldering the bath temperature typically is 220°C-230°C and in selective soldering, the working temperature typically is 240°C-250°C. This substantially reduces the risk of damaging temperature sensitive components and PCB materials and even facilitates the use of cheaper components and materials that are temperature sensitive. In reflow soldering the low melting point alloy also gives lower voiding on BTCs (Bottom Terminated Components). In general low melting point alloys have lower than 10% voiding where lead-free SAC alloys typically have 20-30% of voiding. In wave soldering the low melting point alloy allows for faster production speeds up to 70% and in selective soldering where the soldering of connectors can be done up to 50mm/s the total process time can be reduced by half, increasing the machine capacity with 100%. Furthermore the low melting point alloy does not have problems with good through hole fill on thermally heavy components. The use of nitrogen for wave and reflow soldering is possible but not required. The thermal, electrical and mechanical properties of the LMPA-Q low melting point alloy are sufficient for most electronic applications. Given all these advantages, many see the low melting point alloys as the future of electronics manufacturing.
Lead-based alloys are the traditional SnPb(Ag) based alloys that were used to connect electronic components to PCB (Printed Circuit Board) boards in electronics manufacturing before 2006. In 2006 legislation restricted the use of lead (Pb) because of the risk that end-of-life electronics in land fills would pollute groundwater and Pb would be introduced in the ecosystem. When Pb is taken in by the human body, it is very hard to be removed and it is known to cause all kinds of (long term) health issues. For this reason electronics manufacturing introduced lead-free soldering alloys. As the long term reliability of the lead-free alloys was at that point (2006) not yet established, some critical branches of the electronics industry like e.g. automotive, railway,medical, military,... were allowed to temporarily continue using the SnPb(Ag) alloys. But also in these branches the use of lead-based alloys is gradually being phased out. The most typical alloys for wave soldering were Sn60Pb40 and Sn63Pb37 with melting point around 183°C. This facilitated operating temperatures around 250°C. The oxydation behavior of the alloys was considered acceptable and the use of a closed nitrogen atmosphere like for lead-free alloys was not necessary. For reflow soldering, the most typical alloy was Sn62Pb36Ag2 with melting point around 179°C. The addition of Ag gives extra mechanical reliability to the SMD (Surface Mount Device) solder joints who are typically less strong than through solder joints. The alloy facilitated (measured) peak temperatures in between 200-230°C. The use of nitrogen in reflow was existing but certainly not as widespread as with lead-free alloys.